Surface-directed spinodal decomposition in the pseudobinary alloy (HfO_2)_x(SiO_2)_{1-x}

Hf silicate films (HfO_2)_{0.25}(SiO_2)_{0.75} with thicknesses in the range 4-20 nm were grown on silicon substrate by atomic layer deposition at 350 deg.C.The Hf distributions in as-grown and 800 deg.C annealed films were investigated by high resolution transmission electron microscopy (HRTEM), angle-resolved x-ray photoelectron spectroscopy (ARXPS) and medium energy ion scattering (MEIS). HRTEM images show a layered structure in films thinner than 8 nm. The ARXPS data also reveal a non-uniform distribution of Hf throughout the film depth. Diffusion of SiO_2 to the film surface after a longer time anneal was observed by MEIS. All these observations provide evidence for surface-directed spinodal decomposition in the pseudobinary (HfO_2)_x(SiO_2)_{1-x} alloy system.Comment: 1o figures, one tabl

Cognition and violent behavior in psychotic disorders: a nationwide case-control study

Background: The excess risk of violence in psychotic disorders may partly be explained by impairments in executive functions (EFs) and theory of mind (ToM). However, previous studies have been limited by composite measures of EFs and small samples of inpatients. Methods: Data were collected for the research project Genetic Risk and Outcome of Psychosis (GROUP). Patients with psychotic disorders (N=891) were recruited from various care settings in the Netherlands. The following neuropsychological tests were administered (targeted cognitive function in parentheses): (i) Continuous Performance Test-HQ (inhibition); (ii) Response Shifting Task (cognitive flexibility); (iii) Wechsler Adult Intelligence Scale, Third Edition (WAIS-III) Block Design subtest (fluid intelligence); (iv) Neuropsychological Assessment Battery (NAB) Mazes Test (planning); (v) Degraded Facial Affect Recognition Task (affective ToM); and (vi) Hinting Task (cognitive ToM). Lifetime violence was ascertained from medical records and patient interviews. We used analysis of covariance to compare the mean scores of violent and nonviolent patients on each test, adjusting for age and sex. Results: Violent patients performed significantly worse than nonviolent patients on the WAIS-III Block Design subtest (F [1, 847]=5.12, p=.024), NAB Mazes Test (F [1, 499]=5.32, p=.022) and Hinting Task (F [1, 839]=9.38, p=.002). For the other tests, the between-group differences were nonsignificant. Violent behavior explained no more than 1% of the variance in performance on each test. Conclusion: Impairments in EFs and ToM are unlikely to provide useful targets for risk assessment and interventions

A theoretical study of the aerodynamic characteristics of lifting-body entry vehicles Summary report, Mar. 1965 - Mar. 1966

Aerodynamic characteristics of lifting-body entry vehicle

Phase-ordering of conserved vectorial systems with field-dependent mobility

The dynamics of phase-separation in conserved systems with an O(N) continuous symmetry is investigated in the presence of an order parameter dependent mobility M(\phi)=1-a \phi^2. The model is studied analytically in the framework of the large-N approximation and by numerical simulations of the N=2, N=3 and N=4 cases in d=2, for both critical and off-critical quenches. We show the existence of a new universality class for a=1 characterized by a growth law of the typical length L(t) ~ t^{1/z} with dynamical exponent z=6 as opposed to the usual value z=4 which is recovered for a<1.Comment: RevTeX, 8 pages, 13 figures, to be published in Phys. Rev.

Dynamics of Phase Transitions: The 3D 3-state Potts model

In studies of the QCD deconfining phase transition or cross-over by means of heavy ion experiments, one ought to be concerned about non-equilibrium effects due to heating and cooling of the system. In this paper we extend our previous study of Glauber dynamics of 2D Potts models to the 3D 3-state Potts model, which serves as an effective model for some QCD properties. We investigate the linear theory of spinodal decomposition in some detail. It describes the early time evolution of the 3D model under a quench from the disordered into the ordered phase well, but fails in 2D. Further, the quench leads to competing vacuum domains, which are difficult to equilibrate, even in the presence of a small external magnetic field. From our hysteresis study we find, as before, a dynamics dominated by spinodal decomposition. There is evidence that some effects survive in the case of a cross-over. But the infinite volume extrapolation is difficult to control, even with lattices as large as $120^3$.Comment: 12 pages; added references, corrected typo

Phase-field crystal study of grain-boundary premelting

We study the phenomenon of grain-boundary premelting for temperatures below the melting point in the phase-field crystal model of a pure material with hexagonal ordering in two dimensions. We investigate the structures of symmetric tilt boundaries as a function of misorientation for two different inclinations and compute in the grand canonical ensemble the disjoining potential V(w) that governs the fundamental interaction between crystal-melt interfaces as a function of the premelted layer width w. The results reveal qualitatively different behaviors for high-angle grain boundaries that are uniformly wetted, with w diverging logarithmically as the melting point is approached from below, and low-angle boundaries that are punctuated by liquid pools surrounding dislocations, separated by solid bridges. This qualitative difference between high and low angle boundaries is reflected in the w-dependence of the disjoining potential that is purely repulsive (V'(w)<0 for all w) above a critical misorientation, but switches from repulsive at small w to attractive at large w for low angles. In the latter case, V(w) has a minimum that corresponds to a premelted boundary of finite width at the melting point. Furthermore, we find that the standard wetting condition (the grain boundary energy is equal to twice the solid-liquid free energy) gives a much too low estimate of the critical misorientation when a low-temperature value of the grain boundary energy is used. In contrast, a reasonable estimate is obtained if the grain boundary energy is extrapolated to the melting point, taking into account both the elastic softening of the material at high temperature and local melting around dislocations.Comment: 24 pages, 13 figures, some figure files with reduced resolution because of submission size limitations. In the 2nd version, some parts (and figures) have been modified, especially in Sec. V (discussion

Metastable helium molecules as tracers in superfluid liquid 4^{4}He

Metastable helium molecules generated in a discharge near a sharp tungsten tip operated in either pulsed mode or continuous field-emission mode in superfluid liquid $^{4}$He are imaged using a laser-induced-fluorescence technique. By pulsing the tip, a small cloud of He$_{2}^{*}$ molecules is produced. At 2.0 K, the molecules in the liquid follow the motion of the normal fluid. We can determine the normal-fluid velocity in a heat-induced counterflow by tracing the position of a single molecule cloud. As we run the tip in continuous field-emission mode, a normal-fluid jet from the tip is generated and molecules are entrained in the jet. A focused 910 nm pump laser pulse is used to drive a small group of molecules to the vibrational $a(1)$ state. Subsequent imaging of the tagged $a(1)$ molecules with an expanded 925 nm probe laser pulse allows us to measure the velocity of the normal fluid. The techniques we developed demonstrate for the first time the ability to trace the normal-fluid component in superfluid helium using angstrom-sized particles.Comment: 4 pages, 7 figures. Submitted to Phys. Rev. Let

Calibration of liquid argon and neon detectors with 83Krm^{83}Kr^m

We report results from tests of $^{83}$Kr$^{\mathrm{m}}$, as a calibration source in liquid argon and liquid neon. $^{83}$Kr$^{\mathrm{m}}$ atoms are produced in the decay of $^{83}$Rb, and a clear $^{83}$Kr$^{\mathrm{m}}$ scintillation peak at 41.5 keV appears in both liquids when filling our detector through a piece of zeolite coated with $^{83}$Rb. Based on this scintillation peak, we observe 6.0 photoelectrons/keV in liquid argon with a resolution of 6% ($\sigma$/E) and 3.0 photoelectrons/keV in liquid neon with a resolution of 19% ($\sigma$/E). The observed peak intensity subsequently decays with the $^{83}$Kr$^{\mathrm{m}}$ half-life after stopping the fill, and we find evidence that the spatial location of $^{83}$Kr$^{\mathrm{m}}$ atoms in the chamber can be resolved. $^{83}$Kr$^{\mathrm{m}}$ will be a useful calibration source for liquid argon and neon dark matter and solar neutrino detectors.Comment: 7 pages, 12 figure